Air - Molecular Weight and Composition

Calculate and explore the molecular weight and composition of dry air, including major and minor gas components. Understand how the average molar mass of air is determined from its constituent gases.

ComponentFormulaVolume Ratio (mol/molair)Molar Mass (g/mol)Molar Mass in Air (g/molair)Weight % (wt%)
NitrogenN20.7808428.01321.87398375.52
OxygenO20.2094631.9996.70246923.14
ArgonAr0.0093439.9480.3731141.29
Carbon dioxideCO20.0003344.0100.0146770.051
NeonNe0.0000181820.1800.0003670.0013
HeliumHe0.000005244.0030.0000210.00007
MethaneCH40.0000017916.0420.0000290.00010
KryptonKr0.000001083.7980.0000840.00029
HydrogenH20.00000052.0160.0000010.000003
XenonXe0.00000009131.2930.0000120.00004
Average molar mass of air28.9647100.00

Calculation Method

The average molar mass of air is calculated using the formula:

Mmixture = x₁M₁ + ... + xₙMₙ

Where:

  • xᵢ = mole fractions of each gas
  • Mᵢ = the molar mass of each gas

Key Components

Dry air is composed primarily of:

  • 78.084 vol% Nitrogen (N₂) with molar mass ~28 g/mol
  • 20.946 vol% Oxygen (O₂) with molar mass ~32 g/mol
  • 0.934 vol% Argon (Ar) with molar mass ~40 g/mol
  • Trace amounts of CO₂, Ne, He, CH₄, Kr, H₂, and Xe

Average Molar Mass of Dry Air: 28.9647 g/mol

Air Density

The density of dry air can be calculated using the Ideal Gas Law:

ρ = P / (R·T)

Where:

  • P = pressure (Pa)
  • R_air = 287.05 J/kg·K (individual gas constant)
  • T = absolute temperature (K)

Example: At atmospheric pressure (101.325 kPa) and 0°C (273.15 K): ρ = 1.292 kg/m³

Water Vapor Note

⚠️ Important: Water vapor (H₂O) is lighter than both O₂ and N₂, so dry air is denser than humid air. Water vapor dilutes the other gases and reduces the total density of the mixture.