Vapor and Steam

An introduction to vapor and steam - understanding the properties, states, and characteristics of vapor and steam including saturated vapor, superheated vapor, and steam pressure classifications.

Vapor and Steam

Vapor is a gas - there is no significant physical or chemical difference between a vapor and a gas.

Definition

A vapor is a substance in gaseous state - at a condition where it is ordinarily a liquid or a solid.

The most common example of a vapor is steam - water vaporized during boiling or evaporation.

Key Concepts

Evaporation

Evaporation from a fluid takes place when liquid molecules at the liquid surface have enough momentum to overcome the intermolecular cohesive forces and escape to the atmosphere.

  • Increased heat → increased molecular momentum and evaporation
  • Increased pressure above a liquid → reduces evaporation
  • Reduced pressure above a liquid → increases evaporation

Common Terms

Boiling: Formation of vapor bubbles within a fluid, initiated when absolute pressure reaches vapor pressure.

Saturated Vapor: Vapor at the temperature of the boiling point corresponding to its pressure.

Wet Saturated Vapor: Carries liquid globules in suspension; does not follow the general gas law.

Dry Saturated Vapor: Free from liquid particles; all particles are vaporized.

Super-heated Vapor: Temperature is higher than the boiling point temperature corresponding to the pressure; highly superheated vapors approximate the general gas law.

High Pressure Steam: Steam where pressure greatly exceeds atmospheric pressure.

Low Pressure Steam: Steam where pressure is less than, equal to, or not greatly above atmospheric pressure.

Vapor/Steam TypeDescriptionKey Characteristics
Saturated VaporVapor at boiling point temperatureIn equilibrium with liquid phase
Wet Saturated VaporContains liquid globulesDoes not follow general gas law
Dry Saturated VaporFree from liquid particlesAll particles vaporized
Superheated VaporTemperature above boiling pointApproximately follows gas law when highly superheated
High Pressure SteamHigh pressure relative to atmospherePressure greatly exceeds atmospheric pressure
Low Pressure SteamLow pressure relative to atmospherePressure ≤ atmospheric pressure